Military-related Heavy Metal Pollution in Soil

A Scientific Review

doi: 10.32567/hm.2026.2.5

Abstract

It is well known that during armed conflicts, as well as military trainings, large amounts of pollutants can be released into nature. Of the eleven environmentally toxic elements, Pb, Zn and Cu are often present in high concentrations in the soils of military sites, along with Cd and As. According to newer data from the Russo–Ukrainian War, the inorganic contaminants (mostly toxic elements) show a concentrical distribution in the affected areas, caused by artillery activity; however, the spatial distribution of Pb in the training sites is more dispersed.

Risk assessment, then physicochemical and bioremediation methods can be used for cleaning up the polluted areas from the contaminants after the closure of the armed conflicts or training; however, the complexity, caused by the contaminant mixtures and the great variability of soil components, of the pollution affects the success of the procedure heavily.

Keywords:

soil contamination military geochemistry ordnance remediation

How to Cite

Stadler, T. (2026). Military-related Heavy Metal Pollution in Soil: A Scientific Review. Military Engineer, 21(2), 75–85. https://doi.org/10.32567/hm.2026.2.5

References

AHMAD, Mahtab – MOON, Deok Hyun – LIM, Kyoung Jae – SHOPE, Christopher L. – LEE, Sang Soo – USMAN, Adel R. A. – KIM, Kwon-Rae – PARK, Jeong-Hun – HUR, Seung-Oh –YANG, Jae E. – OK, Yong Sik (2012a): An Assessment of the Utilization of Waste Resources for the Immobilization of Pb and Cu in the Soil from a Korean Military Shooting Range. Environmental Earth Sciences, 67(4), 1023–1031. Online: https://doi.org/10.1007/s12665-012-1550-1

AHMAD, Mahtab – LEE, Sang Soo – YANG, Jae E. – RO, Hee-Myong – HAN LEE, Young – OK, Yong Sik (2012b): Effects of Soil Dilution and Amendments (Mussel Shell, Cow Bone, and Biochar) on Pb Availability and Phytotoxicity in Military Shooting Range Soil. Ecotoxicology and Environmental Safety, 79, 225–231. Online: https://doi.org/10.1016/j.ecoenv.2012.01.003

ALLOWAY, Brian J. (2013): Sources of Heavy Metals and Metalloids in Soils. In ALLOWAY, Brian J. (ed.): Heavy Metals in Soils. Trace Metals and Metalloids in Soils and their Bioavailability. Dordrecht: Springer, 11–50. Online: https://doi.org/10.1007/978-94-007-4470-7_2

ALTAHAAN, Zena – DOBSLAW, Daniel (2024): The Impact of War on Heavy Metal Concentrations and the Seasonal Variation of Pollutants in Soils of the Conflict Zone and Adjacent Areas in Mosul City. Environments, 11(11). Online: https://doi.org/10.3390/environments11110247

BAAH, Douglas S. – FOSU-ASANTE, David – AGYEKUM, Crentsil Kofi – EDZESI, Wisdom Mawuli – ACHEAMPONG, Eric B. (2024): Geochemical Assessment of Metals in Soils and Food Crops around Alluvial Gold Mining in Abuakwa South Municipal, Ghana. Soil and Sediment Contamination, 33(5), 543–559. Online: https://doi.org/10.1080/15320383.2023.2225624

BECH, Jaume – ABREU, Maria M. – CHON, Hyo-Taek – ROCA, Núria (2014): Remediation of Potentially Toxic Elements in Contaminated Soils. In BINI, Claudio – BECH, Jaume (eds.): PHEs, Environment and Human Health. Potentially Harmful Elements in the Environment and the Impact on Human Health. Dordrecht: Springer, 253–308. Online: https://doi.org/10.1007/978-94-017-8965-3_7

CHAMORRO, Andrés F. – SÁNCHEZ-ANDICA, Rubén A. (2024): Understanding the Leaching Dynamics of Lead (Pb+2) in Artificial Soils under Different Conditions. Agronomy, 14(7). Online: https://doi.org/10.3390/agronomy14071520

DAI, Sen – WANG, Zhe – ZENG, Qiuping – ZHANG, Gang (2024): Research on the Application of Comprehensive Physical Exploration in the Detection of Heavy Metal Contaminated Sites – Take the Case of Jijie Town in Yunnan Province as an Example. 2024 Photonics and Electromagnetics Research Symposium (PIERS), Chengdu, 21–25 April 2024. Online: https://doi.org/10.1109/PIERS62282.2024.10618058

DENTON, Gary R. W. – EMBORSKI, Carmen A. – HACHERO, April A. B. – MASGA, Ray S. – STARMER, John A. (2016): Impact of WWII Dumpsites on Saipan (CNMI): Heavy Metal Status of Soils and Sediments. Environmental Science and Pollution Research, 23(11), 11339–11348. Online: https://doi.org/10.1109/PIERS62282.2024.10618058

DU, Yan-Jun – JIANG, Ning-Jun (2022): Stabilization/solidification of Contaminated Soils: A Case Study. In TSANG, Daniel C. W. – WANG, Lei (eds.): Low Carbon Stabilization and Solidification of Hazardous Wastes. Amsterdam: Elsevier, 75–92. Online: https://doi.org/10.1016/B978-0-12-824004-5.00007-4

FAN, Tingting et al. (2022): Meta-analysis of Cd Input-output Fluxes in Agricultural Soil. Chemosphere, 303. Online: https://doi.org/10.1016/j.chemosphere.2022.134974

FAYIGA, Abioye O. – SAHA, Uttam K. (2016): Soil Pollution at Outdoor Shooting Ranges: Health Effects, Bioavailability and Best Management Practices. Environmental Pollution, 216, 135–145. Online: https://doi.org/10.1016/j.envpol.2016.05.062

FREEZE, R. Allan – Cherry, John A. (1979): Groundwater. Englewood Cliffs: Prentice-Hall.

FÜGEDI, Ubul (2004): Geokémiai háttér és nehézfémszennyezés Gyöngyösoroszi térségében [Geochemical Background and Heavy Metal Pollution Near Gyöngyösoroszi (NE Hungary)]. Földtani Közlöny, 134(2), 291–301.

HANSEN, Henrik K. – OTTOSEN, Lisbeth M. – KLIEM, Bodil K. – VILLUMSEN, Arne (1997): Electrodialytic Remediation of Soils Polluted with Cu, Cr, Hg, Pb and Zn. Journal of Chemical Technology and Biotechnology, 70(1), 67–73. Online: https://doi.org/10.1002/(SICI)1097-4660(199709)70:1<67::AID-JCTB662>3.0.CO;2-V

HOOKER, Paul J. – NATHANAIL, C. Paul (2006): Risk-based Characterisation of Lead in Urban Soils. Chemical Geology, 226(3–4), 340–351. Online: https://doi.org/10.1016/j.chemgeo.2005.09.028

KORRE, Anna – DURUCAN, Şevket – KOUTROUMANI, A. (2002): Quantitative-spatial Assessment of the Risks Associated with High Pb Loads in Soils around Lavrio, Greece. Applied Geochemistry, 17(8), 1029–1045. Online: https://doi.org/10.1016/S0883-2927(02)00058-6

LI, Jining – HASHIMOTO, Yohey – RIYA, Shohei – TERADA, Akihiko – HOU, Hong – SHIBAGAKI, Yuichi – HOSOMI, Masaaki (2019): Removal and Immobilization of Heavy Metals in Contaminated Soils by Chlorination and Thermal Treatment on an Industrial-scale. Chemical Engineering Journal, 359, 385–392. Online: https://doi.org/10.1016/j.cej.2018.11.158

LI, Yuntao – GAO, Yan – CHEN, Wei – ZHANG, Weiguo – LU, Xin (2024): Shifts in Bacterial Diversity, Interactions and Microbial Elemental Cycling Genes under Cadmium Contamination in Paddy Soil: Implications for Altered Ecological Function. Journal of Hazardous Materials, 461. Online: https://doi.org/10.1016/j.jhazmat.2023.132544

LI, Zhu – MA, Tingting – YUAN, Cheng – HOU, Jinyu – WANG, Qingling – WU, Longhua –CHRISTIE, Peter – LUO, Yongming (2016): Metal Contamination Status of the Soil-Plant System and Effects on the Soil Microbial Community Near a Rare Metal Recycling Smelter. Environmental Science and Pollution Research, 23(17), 17625–17634. Online: https://doi.org/10.1007/s11356-016-6958-9

LU, Kouping et al. (2017): Effect of Bamboo and Rice Straw Biochars on the Mobility and Redistribution of Heavy Metals (Cd, Cu, Pb and Zn) in Contaminated Soil. Journal of Environmental Management, 186, 285–292. Online: https://doi.org/10.1016/j.jenvman.2016.05.068

MANDUCA, Paola – AL BARAQUNI, Nabil – PARODI, Stefano (2020): Long Term Risks to Neonatal Health from Exposure to War – 9 Years Long Survey of Reproductive Health and Contamination by Weapon-delivered Heavy Metals in Gaza, Palestine. International Journal of Environmental Research and Public Health, 17(7). Online: https://doi.org/10.3390/ijerph17072538

MEES, Florias – MASALEHDANI, M. Naze Nancy – DE PUTTER, Thierry – D’Hollander, C. – van Biezen, E. – BAZIRAKE MUJINYA, Basile – POTDEVIN, Jean Luc – VAN RANST, Eric V. (2013): Concentrations and Forms of Heavy Metals around Two Ore Processing Sites in Katanga, Democratic Republic of Congo. Journal of African Earth Sciences, 77, 22–30. Online: https://doi.org/10.1016/j.jafrearsci.2012.09.008

MOLISZEWSKA, Ewa – BIDA, Iryna – MATIK, Kacper – ŚLUSARCZYK, Aleksandra – PAWLICZEK, Dominik – HAVRYLIUK, Olesia – HOVORUKHA, Vira – TASHYREV, Oleksandr (2025): Analysis of Variations in Heavy Metal Levels and Soil Microorganism Counts Resulting from Shelling Incidents in Ukraine. Archives of Environmental Protection, 51(1), 83–91. Online: https://doi.org/10.24425/aep.2025.153752

NÉMETH, Tibor – JIMÉNEZ-MILLÁN, Juan – SIPOS, Péter – ABAD, Isabel – JIMÉNEZ-ESPINOSA, Rosario – SZALAI, Zoltán (2011): Effect of Pedogenic Clay Minerals on the Sorption of Copper in a Luvisol B Horizon. Geoderma, 160(3–4), 509–516. Online: https://doi.org/10.1016/j.geoderma.2010.09.031

ORCINO, Michael A. – BRICKA, R. Mark (1998): Electrochemical Remediation of Heavy Metal Contaminated Soils. Remediation, 9(1), 23–47. Online: https://doi.org/10.1002/rem.3440090104

OTTOSEN, Lisbeth M. – KRISTENSEN, Iben V. – PEDERSEN, Anne J. – HANSEN, Henrik K. – VILLUMSEN, Arne – RIBEIRO, Alexandra B. (2003): Electrodialytic Removal of Heavy Metals from Different Solid Waste Products. Separation Science and Technology, 38(6), 1269–1289. Online: https://doi.org/10.1081/SS-120018809

PETRUSHKA, Kateryna – PETRUSHKA, Ihor (2025): Ecological Risks of Chromium Contamination in Ukrainian Soils Affected by Military Activity: SEM-EDS and EPMA Analysis. Environmental Problems, 10(3), 298–309. Online: https://doi.org/10.23939/ep2025.03.298

POPOOLA, Olaniyi J. – OGUNDELE, Olusola D. – LADAPO, Emmanuel A. – SENBORE, Samson (2024): The Impact of Heavy Metal Contamination in Soils on Soil Microbial Communities and Its Potential Health Risks for Humans. In ARANSIOLA, Sesan A. – ATTA, Habiba I. – MADDELA, Naga R. (eds.): Soil Microbiome in Green Technology Sustainability. Cham: Springer, 351–375. Online: https://doi.org/10.1007/978-3-031-71844-1_15

RAHEEMAH, Oday H. – KADHIM, Inaam H. – BOUDAYA, Chokri (2025): Measuring Uranium Levels in Nail Samples of Cancer Patients in Babylon Governorate, Iraq. Environment Asia, 18(3), 158–169. Online: https://doi.org/10.14456/ea.2025.59

REEVES, Roger D. – BAKER, Alan J. M. – JAFFRÉ, Tanguy – ERSKINE, Peter D. – ECHEVARRIA, Guillaume – VAN DER ENT, Antony (2018): A Global Database for Plants that Hyperaccumulate Metal and Metalloid Trace Elements. New Phytologist, 218(2), 407–411. Online: https://doi.org/10.1111/nph.14907

SANDERSON, Peter – THANGAVADIVEL, Kandasamy – RANGANATHAN, Srinivasan –CHADALAVADA, Sreenivasulu – NAIDU, Ravi – BOWMAN, Mark (2019): Effectiveness of Gravity Based Particle Separation and Soil Washing for Reduction of Pb in a Clay Loam Shooting Range Soil. Environmental Technology and Innovation, 16. Online: https://doi.org/10.1016/j.eti.2019.100480

SINGH, Shailendra K. – SUBRAMANIAN, V. – GIBBS, Ronald J. (1984): Hydrous FE and MN oxides — scavengers of heavy metals in the aquatic environment. Critical Reviews in Environmental Control, 14(1), 33–90. Online: https://doi.org/10.1080/10643388409381713

SIPOS, Péter (2009): Distribution and Sorption of Potentially Toxic Metals in Four Forest Soils from Hungary. Central European Journal of Geosciences, 1(2), 183–192. Online: https://doi.org/10.2478/v10085-009-0009-4

SKALNY, Anatoly V. – ASCHNER, Michael – BOBROVNITSKY, Igor P. – CHEN, Pan – TSATSAKIS, Aristidis – PAOLIELLO, Monica M. B. – BUHA DJORDEVIC, Aleksandra – TINKOV, Alexey A. (2021): Environmental and Health Hazards of Military Metal Pollution. Environmental Research, 201. Online: https://doi.org/10.1016/j.envres.2021.111568

SONG, Jinkun – TOWNSEND, Timothy – SOLO-GABRIELE, Helena – JANG, Yong-Chul (2006): Hexavalent Chromium Reduction in Soils Contaminated with Chromated Copper Arsenate Preservative. Soil and Sediment Contamination, 15(4), 387–399. Online: https://doi.org/10.1080/15320380600751751

SPLODYTEL, Anastasiia (2020): Ландшафтно-геохімічні умови та закономірності розподілу токсичних елементів на території військового полігону “Олешківські піски” [Landscape and Geochemical Preconditions and Patterns of Toxic Element Distribution at the “Oleshky Sands” Military Training Range]. Mineral Resources of Ukraine, (1), 34–43. Online: https://doi.org/10.31996/mru.2020.1.34-43

SZŰCS-VÁSÁRHELYI, Nóra (2019): A talajszennyezésről általában, különös tekintettel a szervetlen szennyező anyagokra [Soil Pollution in General, with Particular Regard to Inorganic Pollutants]. Hadmérnök, 14(4), 127–146. Online: https://doi.org/10.32567/hm.2019.4.8

TEŠAN TOMIĆ, Neda – SMILJANIĆ, Slavko – JOVIĆ MIHANOVIĆ, Marija – GLIGORIĆ, Miloš –POVRENOVIĆ, Dragan – DOŠIĆ, Aleksandar (2018): Examining the Effects of the Destroying Ammunition, Mines and Explosive Devices on the Presence of Heavy Metals in Soil of Open Detonation Pit; Part 2: Determination of Heavy Metal Fractions. Water, Air, & Soil Pollution, 229(9),1–20. Online: https://doi.org/10.1007/s11270-018-3950-7

WIJNGAARD, René R. – VAN DER PERK, Marcel – VAN DER GRIFT, Bas – DE NIJS, Ton C. M. –BIERKENS, Marc F. P. (2017): The Impact of Climate Change on Metal Transport in a Lowland Catchment. Water, Air, and Soil Pollution, 228(3). Online: https://doi.org/10.1007/s11270-017-3261-4

XU, Zixin – YIN, Ming – YANG, Xue – YANG, Yong – XU, Xuehui – LI, Haigang – HONG, Mei – QIU, Guohong – FENG, Xionghan – TAN, Wenfeng – YIN, Hui (2024): Simulation of Vertical Migration Behaviors of Heavy Metals in Polluted Soils from Arid Regions in Northern China under Extreme Weather. Science of the Total Environment, 919. Online: https://doi.org/10.1016/j.scitotenv.2024.170494

YAASHIKAA, Ponnambalam R. – SENTHIL KUMAR, P. – SATHASIVAM, Jeevanantham – RAJENDRAN, Saravanan (2022): A Review on Bioremediation Approach for Heavy Metal Detoxification and Accumulation in Plants. Environmental Pollution, 301. Online: https://doi.org/10.1016/j.envpol.2022.119035

YANG, Xing – LIU, Jingjing – MCGROUTHER, Kim – HUANG, Huagang – LU, Kouping – GUO, Xi – HE, Lizhi – LIN, Xiaoming – CHE, Lei – YE, Zhengqian – WANG, Hailong (2016): Effect of Biochar on the Extractability of Heavy Metals (Cd, Cu, Pb, and Zn) and Enzyme Activity in Soil. Environmental Science and Pollution Research, 23(2), 974–984. Online: https://doi.org/10.1007/s11356-015-4233-0

YASHCHENKO, Liudmyla – Androshchuk, Oleksandr – VASYLENKO, Liudmyla – CHORNOIVAN, Yuliya (2025): Environmental Risks of Heavy Metal Pollution in War-Affected Soils in Ukraine. European Journal of Environmental Sciences, 15(1), 18–27. Online: https://doi.org/10.14712/23361964.2025.3